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Solids and Surfaces: A Chemist's View of Bonding in Extended Structures, by Roald Hoffmann
Ebook Free Solids and Surfaces: A Chemist's View of Bonding in Extended Structures, by Roald Hoffmann
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This unique book shows how chemistry and physics come together in the solid state and on surfaces. Using a lively, graphic, descriptive approach, it teaches chemists the language that is necessary to understand the electronic structure of extended systems. And, at the same time, it demonstrates how a chemical, frontier-orbital, approach to solid state and surface bonding and reactivity may be constructed.
The book begins with the language of crystal orbitals, band structures and densities of states. The tools for moving back from the highly delocalized orbitals of the solid are then built up in a transparent manner; they include decompositions of the densities of states and crystal orbital overlap populations. Using these tools, the book shapes a meeting ground between detailed quantum mechanical calculations and a chemical frontier orbital perspec- tive. Applications include a general picture of chemisorption, bond-breaking and making in the solid state, bonding in metals, the electronic structure of selected conducting and supercon- ducting structures, dissociation, migration and coupling on surfaces and the forces controlling deformation of extended systems.
- Sales Rank: #1259900 in Books
- Published on: 1989-01-13
- Original language: English
- Number of items: 1
- Dimensions: 8.74" h x .56" w x 5.81" l, .79 pounds
- Binding: Hardcover
- 152 pages
Most helpful customer reviews
5 of 5 people found the following review helpful.
A straightforward, visual examination of a difficult subject
By Craig MACKINNON
This book bridges the language gap between chemistry and condensed matter physics. Starting from the language that all chemists are comfortable with - that of molecular orbitals - Hoffman builds up the idea of bonding in extended structures (solids) as if a solid was just a giant molecule. This is done with a minimum of mathematics, mostly using simple and graphical representation. As a primer to the area of solid state chemistry, this book is invaluable.
I'm not sure if physicists, starting from the other end of the language will find it as useful as a chemist, but it should be straightforward for them as well, giving them the chemist's point of view (language).
This is a short book, and wisely does not try to exceed its boundries, that of an introduction/overview. For a more mathematical treatment, I would suggest Burdett's "Chemical Bonding in Solids." If you only want an introduction written in plain language with lots of graphics, this is the book for you.
0 of 0 people found the following review helpful.
Every chemist needs to read this!
By David L Eaton
This book bridges a gap between molecular orbital theory and the empirical/intuitive way chemists think about bonding in molecules. From there, it opens up vistas in extended systems (e.g. solids, conductive polymers) that most ordinary "molecular" chemists think of as foreign and forbidding because the language and tools used to treat them are those of solid state physicists with which most chemists are (regrettably) unfamiliar. Hoffmann brings all this good stuff home to chemists, without the bludgeon of complicated mathematics, inviting us in, showing us how much we already know. My own background is both physics and traditional synthetic organic/organometallic chemistry. Until I read this book, I had struggled to see how the physics and chemistry meet. This book has really bridged the gap.
1 of 1 people found the following review helpful.
Conceptually brilliant !
By Nuno A. G. Bandeira
This is simply the funniest and most enjoyable book on theoretical inorganic chemistry I've ever read. Its format is close to your typical bedside table novel, lively informal and packed with the most awesome qualitative insights on bonding with molecular orbital theory without the need to resort to hardcore mathematics. It also has some amusing puns and jokes mixed with the enthusiasm of conveying this knowledge. The more interested reader should also read Jeremy Burdett's "Chemical Bonding in Solids" for a more detailed account of the quantum chemical and solid state aspects involved. All in all 140 pages of pure pleasure.
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